Fullerene bisadduct stabilizers: The effect of different addition positions on inhibiting the autocatalytic decomposition of nitrocellulose absorbed nitroglycerin

To explore the effect of different positions and number of pyrrolidine bound to the carbon cage on the stabilization effect of fulleropyrrolidine derivatives to nitrocellulose (NC)/nitroglycerine (NG), we synthesized N-(4-methoxy) phenylpyrrolidine-C₆₀ and four different of bis(N-(4-methoxy) phenylpyrrolidine)-C₆₀ compounds through Prato reaction. Their structures were characterized by UV–vis, ¹H NMR, ¹³C NMR, high-resolution mass spectroscopy, and single-crystal X-ray diffraction. Their stabilization effect to NC/NG were investigated using differential scanning calorimetry, methyl violet, vacuum stabilization effect, weight loss, and accelerating rate calorimeter tests. The results indicated these compounds had excellent stabilization effect to NC/NG. The stabilization effect of the fulleropyrrolidine bisadducts to NC/NG is significantly better than that of fulleropyrrolidine monoadduct and C₆₀. Moreover, the position where pyrrolidine binds to fullerene in fulleropyrrolidine bisadducts is different, and its stabilization effect to NC is also different. The stabilization effect order of different bisadduct isomers to nitrocellulose is as follows: e-edge > trans-2> cis-2> trans-3. Electron paramagnetic resonance (EPR) and FT-IR were used to study the stabilization mechanism of fulleropyrrolidine derivatives to NC/NG. The EPR results also show that fulleropyrrolidine bisadducts with different addition sites have different abilities to absorb nitroxide, and their ability is better than that of the monoadduct and C₆₀, which is consistent with the results of stabilization effect performance test.     

多旋翼无人机模型预测抗扰避障制导

多旋翼无人机的自主避障是完成复杂任务的基础,避障的效果直接影响无人机执行任务的效能。针对存在外部扰动的无人机避障问题,提出了一种基于模型预测的抗扰避障制导律设计方法。通过设计干扰观测器对系统动态中的外部干扰进行了估计,并基于李雅普诺夫函数方法设计辅助制导律用于建立稳定性约束条件。结合前两者与模型预测控制,在模型预测控制优化求解中考虑无人机与障碍物的关系,根据所设计的制导律求解水平线速度与偏航角速度指令实现无人机的避障。对所提出的避障制导律进行数值〖BHDWG8,WK10YQ,DK1*2,WK1*2D〗〖XCLQX.TIF;%129%129〗听语音 聊科研与作者互动 仿真和实物飞行验证,结果表明了所提方法的有效性。     

基于HLA的导弹攻防仿真系统分析与设计

基于HLA建立仿真应用系统是提高作战仿真活动效率的有效途径。分析了导弹攻防仿真系统的组成和特点,在联邦开发与执行过程模型(FEDEP)基础上,结合作者的开发经验,探讨了基于HLA的仿真应用系统开发的一般过程,将其总结为系统分析、联邦设计、FOM/SOM开发、联邦成员实现与联邦集成四个步骤。给出了某地地导弹与宙斯盾防御系统攻防仿真的系统设计实例。     

捷联式惯性导航系统误差处理技术的新进展

捷联式惯性导航系统误差处理的研究在近年来取得很大进展 ,相继出现了一些新思想、新算法、新技术。首先对捷联惯导系统误差模型的研究现状作了系统总结 ,然后对捷联式系统姿态算法和误差处理技术进行了归纳和分析 ,重点介绍了近期出现的几种新技术 ,最后提出了捷联惯导系统误差处理技术的研究方向。     

论高校科技期刊的审稿工作

高校科技期刊现行审稿方法主要是单盲审稿和双盲审稿 ,这种封闭式暗箱操作的方法必然受到一些人为因素的干扰 ,影响审稿的客观和公正 ,从而影响期刊的学术质量。对此 ,在审稿中应加大外审稿的比重 ,启用中青年学者审稿 ,公开审稿和网上审稿。     

Deterministic inventory lot‐size models under inflation with shortages and deterioration for fluctuating demand

In this paper, we extend the inventory lot‐size models to allow for inflation and fluctuating demand (which is more general than constant, increasing, decreasing, and log‐concave demand patterns). We prove that the optimal replenishment schedule not only exists but is also unique. Furthermore, we show that the total cost associated with the inventory system is a convex function of the number of replenishments. Hence, the search for the optimal number of replenishments is simplified to finding a local minimum. Finally, several numerical examples are provided to illustrate the results. © 2001 John Wiley & Sons, Inc. Naval Research Logistics 48: 144–158, 2001     

新形势下高校良好群体关系的构建

随着高校人事制度、分配制度、管理体制的改革 ,高校不同群体间的差异将日趋明显。本文通过对高校不同群体特性的分析 ,提出了构建良好群体关系的必要性和基本途径     

营房实力综合数据分析技术

在营房系统中,营房实力主要包括个人基本情况及住房情况、家属住房情况两大类的知识。营房住房标准分为:按标准住房、超标准住房、未达标准住房、无住房。结合营房实力数据的基本特点,充分利用了先进的数据仓库技术,在数据挖掘和商业智能服务等方面作了深入的探讨,通过营房实力知识对数据进行归类统计,提出了基于知识的统计系统,建立了营房住用多维数据模型和个人住房情况多维数据模型,实现了对营房住用情况和个人住房情况等营房数据的多维分析。     

领导干部经济责任审计风险成因及其防范

当前,领导干部经济责任审计风险的成因主要有外部原因和内部原因两个方面。防范经济责任审计风险,必须创造良好的审计环境,加强审计工作管理,努力提高审计人员的综合素质。     

低压电场驱动下膜分离 CO2的研究

以离子交换膜为基础,进行预处理和化学改性.研究了不同预处理条件、化学改性方法及低压电场的电压对离子交换膜的CO2分离效率的影响.结果表明,改进处理条件、施加低压电场及在膜中加入亲水物质可明显地增加离子交换膜的二氧化碳通量.